Search for: All records

Repeated transects have become the backbone of spatially distributed ice and snow thickness measurements crucial for understanding of ice mass balance. Here we detail the transects at the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) 2019–2020, which represent the first such measurements collected across an entire season. Compared with similar historical transects, the snow at MOSAiC was thin (mean depths of approximately 0.1–0.3 m), while the sea ice was relatively thick first-year ice (FYI) and second-year ice (SYI). SYI was of two distinct types: relatively thin level ice formed from surfaces with extensive melt pond cover, and relatively thick deformed ice. On level SYI, spatial signatures of refrozen melt ponds remained detectable in January. At the beginning of winter the thinnest ice also had the thinnest snow, with winter growth rates of thin ice (0.33 m month−1 for FYI, 0.24 m month−1 for previously ponded SYI) exceeding that of thick ice (0.2 m month−1). By January, FYI already had a greater modal ice thickness (1.1 m) than previously ponded SYI (0.9 m). By February, modal thickness of all SYI and FYI became indistinguishable at about 1.4 m. The largest modal thicknesses were measured in May at 1.7 m. Transects included deformed ice, where largest volumes of snow accumulated by April. The remaining snow on level ice exhibited typical spatial heterogeneity in the form of snow dunes. Spatial correlation length scales for snow and sea ice ranged from 20 to 40 m or 60 to 90 m, depending on the sampling direction, which suggests that the known anisotropy of snow dunes also manifests in spatial patterns in sea ice thickness. The diverse snow and ice thickness data obtained from the MOSAiC transects represent an invaluable resource for model and remote sensing product development.

 

Abstract. Wind-driven redistribution of snow on sea ice alters itstopography and microstructure, yet the impact of these processes on radarsignatures is poorly understood. Here, we examine the effects of snowredistribution over Arctic sea ice on radar waveforms and backscattersignatures obtained from a surface-based, fully polarimetric Ka- and Ku-bandradar at incidence angles between 0∘ (nadir) and 50∘.Two wind events in November 2019 during the Multidisciplinary drifting Observatory forthe Study of Arctic Climate (MOSAiC) expedition are evaluated. During both events, changes in Ka- andKu-band radar waveforms and backscatter coefficients at nadir are observed,coincident with surface topography changes measured by a terrestrial laserscanner. At both frequencies, redistribution caused snow densification atthe surface and the uppermost layers, increasing the scattering at theair–snow interface at nadir and its prevalence as the dominant radar scattering surface. The waveform data also detected the presence of previousair–snow interfaces, buried beneath newly deposited snow. The additionalscattering from previous air–snow interfaces could therefore affect therange retrieved from Ka- and Ku-band satellite altimeters. With increasingincidence angles, the relative scattering contribution of the air–snowinterface decreases, and the snow–sea ice interface scattering increases.Relative to pre-wind event conditions, azimuthally averaged backscatter atnadir during the wind events increases by up to 8 dB (Ka-band) and 5 dB (Ku-band). Results show substantial backscatter variability within the scanarea at all incidence angles and polarizations, in response to increasingwind speed and changes in wind direction. Our results show that snowredistribution and wind compaction need to be accounted for to interpretairborne and satellite radar measurements of snow-covered sea ice.

 

Abstract We investigate how sea ice decline in summer and warmer ocean and surface temperatures in winter affect sea ice growth in the Arctic. Sea ice volume changes are estimated from satellite observations during winter from 2002 to 2019 and partitioned into thermodynamic growth and dynamic volume change. Both components are compared to validated sea ice-ocean models forced by reanalysis data to extend observations back to 1980 and to understand the mechanisms that cause the observed trends and variability. We find that a negative feedback driven by the increasing sea ice retreat in summer yields increasing thermodynamic ice growth during winter in the Arctic marginal seas eastward from the Laptev Sea to the Beaufort Sea. However, in the Barents and Kara Seas, this feedback seems to be overpowered by the impact of increasing oceanic heat flux and air temperatures, resulting in negative trends in thermodynamic ice growth of -2 km 3 month -1 yr -1 on average over 2002-2019 derived from satellite observations. 

Sea ice thickness is a key parameter in the polar climate and ecosystem. Thermodynamic and dynamic processes alter the sea ice thickness. The Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition provided a unique opportunity to study seasonal sea ice thickness changes of the same sea ice. We analyzed 11 large-scale (∼50 km) airborne electromagnetic sea thickness and surface roughness surveys from October 2019 to September 2020. Data from ice mass balance and position buoys provided additional information. We found that thermodynamic growth and decay dominated the seasonal cycle with a total mean sea ice thickness increase of 1.4 m (October 2019 to June 2020) and decay of 1.2 m (June 2020 to September 2020). Ice dynamics and deformation-related processes, such as thin ice formation in leads and subsequent ridging, broadened the ice thickness distribution and contributed 30% to the increase in mean thickness. These processes caused a 1-month delay between maximum thermodynamic sea ice thickness and maximum mean ice thickness. The airborne EM measurements bridged the scales from local floe-scale measurements to Arctic-wide satellite observations and model grid cells. The spatial differences in mean sea ice thickness between the Central Observatory (<10 km) of MOSAiC and the Distributed Network (<50 km) were negligible in fall and only 0.2 m in late winter, but the relative abundance of thin and thick ice varied. One unexpected outcome was the large dynamic thickening in a regime where divergence prevailed on average in the western Nansen Basin in spring. We suggest that the large dynamic thickening was due to the mobile, unconsolidated sea ice pack and periodic, sub-daily motion. We demonstrate that this Lagrangian sea ice thickness data set is well suited for validating the existing redistribution theory in sea ice models. Our comprehensive description of seasonal changes of the sea ice thickness distribution is valuable for interpreting MOSAiC time series across disciplines and can be used as a reference to advance sea ice thickness modeling. 

Abstract. Arctic rain on snow (ROS) deposits liquid water onto existing snowpacks. Upon refreezing, this can form icy crusts at the surface or within the snowpack. By altering radar backscatter and microwave emissivity, ROS over sea ice can influence the accuracy of sea ice variables retrieved from satellite radar altimetry, scatterometers, and passive microwave radiometers. During the Arctic Ocean MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) expedition, there was an unprecedented opportunity to observe a ROS event using in situ active and passive microwave instruments similar to those deployed on satellite platforms. During liquid water accumulation in the snowpack from rain and increased melt, there was a 4-fold decrease in radar energy returned at Ku- and Ka-bands. After the snowpack refroze and ice layers formed, this decrease was followed by a 6-fold increase in returned energy. Besides altering the radar backscatter, analysis of the returned waveforms shows the waveform shape changed in response to rain and refreezing. Microwave emissivity at 19 and 89 GHz increased with increasing liquid water content and decreased as the snowpack refroze, yet subsequent ice layers altered the polarization difference. Corresponding analysis of the CryoSat-2 waveform shape and backscatter as well as AMSR2 brightness temperatures further shows that the rain and refreeze were significant enough to impact satellite returns. Our analysis provides the first detailed in situ analysis of the impacts of ROS and subsequent refreezing on both active and passive microwave observations, providing important baseline knowledge for detecting ROS over sea ice and assessing their impacts on satellite-derived sea ice variables.

 

Abstract. Data from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition allowed us to investigate the temporal dynamics of snowfall, snow accumulation and erosion in great detail for almost the whole accumulation season (November 2019 to May 2020). We computed cumulative snow water equivalent (SWE) over the sea ice based on snow depth and density retrievals from a SnowMicroPen and approximately weekly measured snow depths along fixed transect paths. We used the derived SWE from the snow cover to compare with precipitation sensors installed during MOSAiC. The data were also compared with ERA5 reanalysis snowfall rates for the drift track. We found an accumulated snow mass of 38 mm SWE between the end of October 2019 and end of April 2020. The initial SWE over first-year ice relative to second-year ice increased from 50 % to 90 % by end of the investigation period. Further, we found that the Vaisala Present Weather Detector 22, an optical precipitation sensor, and installed on a railing on the top deck of research vessel Polarstern, was least affected by blowing snow and showed good agreements with SWE retrievals along the transect. On the contrary, the OTT Pluvio2 pluviometer and the OTT Parsivel2 laser disdrometer were largely affected by wind and blowing snow, leading to too high measured precipitation rates. These are largely reduced when eliminating drifting snow periods in the comparison. ERA5 reveals good timing of the snowfall events and good agreement with ground measurements with an overestimation tendency. Retrieved snowfall from the ship-based Ka-band ARM zenith radar shows good agreements with SWE of the snow cover and differences comparable to those of ERA5. Based on the results, we suggest the Ka-band radar-derived snowfall as an upper limit and the present weather detector on RV Polarstern as a lower limit of a cumulative snowfall range. Based on these findings, we suggest a cumulative snowfall of 72 to 107 mm and a precipitation mass loss of the snow cover due to erosion and sublimation as between 47 % and 68 %, for the time period between 31 October 2019 and 26 April 2020. Extending this period beyond available snow cover measurements, we suggest a cumulative snowfall of 98–114 mm. 

Snow depth on sea ice is an Essential Climate Variable and a major source of uncertainty in satellite altimetry‐derived sea ice thickness. During winter of the MOSAiC Expedition, the “KuKa” dual‐frequency, fully polarized Ku‐ and Ka‐band radar was deployed in “stare” nadir‐looking mode to investigate the possibility of combining these two frequencies to retrieve snow depth. Three approaches were investigated: dual‐frequency, dual‐polarization and waveform shape, and compared to independent snow depth measurements. Novel dual‐polarization approaches yieldedr²values up to 0.77. Mean snow depths agreed within 1 cm, even for data sub‐banded to CryoSat‐2 SIRAL and SARAL AltiKa bandwidths. Snow depths from co‐polarized dual‐frequency approaches were at least a factor of four too small and had ar²0.15 or lower.r²for waveform shape techniques reached 0.72 but depths were underestimated. Snow depth retrievals using polarimetric information or waveform shape may therefore be possible from airborne/satellite radar altimeters.

 

We report a transition metal‐free, regio‐ and stereo‐selective, phosphine‐catalyzed method for thetranshydroboration of 1,3‐diynes with pinacolborane that affords (E)‐1‐boryl‐1,3‐enynes. The reaction proceeds with excellent selectivity for boron addition to the external carbon of the 1,3‐diyne framework as unambiguously established by NMR and X‐ray crystallographic studies. The reaction displays a broad substrate scope including unsymmetrical diynes to generate products in high yield (up to 95 %). Experimental and theoretical studies suggest that phosphine attack on the alkyne is a key process in the catalytic cycle.